A customer who arrives on your website at 21u30 may not be able to call you. They can fill in a form and wait for a reply, or choose an available time through a booking link. The right route depends on your service and what you need to know about the enquiry beforehand.
Letting people book appointments online still feels like a big step for many Belgian SMEs: the diary is private territory. But you do not have to open up your entire schedule. Defined appointment types and available hours give visitors a next step when you are unavailable. A booking is an appointment, not automatically a customer or a substantive answer to the enquiry.